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Posts by The Self Taught Man
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2017-03-17 at 1:47 PM UTC in Just did krokodil for the 1st timi wanna make this stuff
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2017-03-17 at 1:46 PM UTC in who comeingCan we havea tek dotz meetup
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2017-03-17 at 1:45 PM UTC in nutmeg is cool
Originally posted by NARCassist what sorta dose would you use of nutmeg? in jail i did a cookery course. there was a large tub of ground nutmeg there, i coulda took loads but dint have any idea how much to use or what the trip was like. i was astounded considering the prison drug situation that it was just sitting the and nobody even had a clue of its potential.
all of them -
2017-03-17 at 1:45 PM UTC in it is possible to make a magnet that only pick up hash?thats the greatest thing I ever heard.
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2017-03-17 at 1:44 PM UTC in Safrole from GuaifenisenGuaifenisin is O-(2,3-dihydroxypropyl)-catechol.
The Lucas reaction with ZnCl2 in concentrated HCl converts this to O-(2,3-dichloropropyl)-catechol. This is the only part that's a little touchy: we need complete conversion here. Cleavage of the phenolic ether is very unlikely, or we'd use HCl/ZnCl2 for eugenol and codeine. The first product is O-(2-chloro-3-hydroxycatechol; the second one is what we want. I hope the monochlorinated product is still water-soluble; the dichlorinated product probably isn't.
The Finkelstein reaction proceeds about a thousand times faster on primary halides than on secondary halides. Using one molar equivalent of NaI, you get exclusive conversion to O-(2-chloro-3-iodopropyl)-catechol.
This can be converted to O-allylcatechol by photolysis in methanol:
http://www.journal.csj.jp/doi/pdf/10.1246/cl.1983.1297
All that's required is light and methanol. Dichlorides give poor yields, but iodochlorides gave over 95% yield.
O-allylcatechol then thermally rearranges (Claisen) to a mixture of 3-allylcatechol and 4-allylcatechol, which can be methylenated.
There are a few steps here, but two of them use no extra reagents at all, and none of this is expensive or very dangerous. -
2017-03-17 at 1:43 PM UTC in Mastubation to be BannedLegalize crystal meth and ban masturbation and put cameras everywhere.
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2017-03-17 at 1:42 PM UTC in Had a really nice dream...
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2017-03-17 at 1:42 PM UTC in cheap btc tonite ()_btc loan thred 3()_fuck the darknet lolololool
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2017-03-17 at 1:41 PM UTC in sum1` loadn me 30 bux
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2017-03-17 at 1:39 PM UTC in teh retraded thred herppppp slober fuk glum editshin
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2017-03-17 at 1:35 PM UTC in S-200 launch reported just now near the GolanHow widespread are your sources? Did the Israelies report about this?
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2017-03-17 at 1:32 PM UTC in sellin shsh to asian studentsFUCK YOU HE MADE A THREAD ABOUT SELLING DRUGS TO ASIANS I SAY SELL THEM FUCKING TEK DOTS FUCK YOU!
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2017-03-17 at 1:31 PM UTC in Intellectual ConversationI will not soon forget that day, you guys betrayed me. Turned your backs against the triangles.
I'll show you... I'll show all of you!. -
2017-03-17 at 1:31 PM UTC in sellin shsh to asian students
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2017-03-17 at 1:29 PM UTC in Intellectual ConversationYou outperform nothing you delusional faggot. You were the one who got banned because of someone else posting Bill Krozby dick.
You got cucked like a motherfucker and nobody gave a shit. -
2017-03-17 at 1:27 PM UTC in Lanny is a real piece of work/shitHow do you know about billiam?.
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2017-03-17 at 1:26 PM UTC in teh retraded thred herppppp slober fuk glum editshinGood song.
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2017-03-17 at 1:26 PM UTC in teh retraded thred herppppp slober fuk glum editshinI haven't slept in 2 days,.
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2017-03-17 at 1:25 PM UTC in Anybody out walking in a neighborhood between 1:00am - 5:00am is probably up to something.i bought two meth pipes so I could do tek dots while I walk around and if the barrys roll up on me I will smash the pipe as hard as I can on the ground and say to the cop "Tek Dotz"
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2017-03-17 at 1:24 PM UTC in Lanny is a real piece of work/shit