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Posts That Were Thanked by mmQ
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2017-04-03 at 2:01 AM UTC in teh retraded thred herppppp slober fuk glum editshin
Originally posted by mmQ So what you're saying is 'sour-lipped bitch-bottom'
id smack you for dat one
I gotta leave this here for storage I will pick it up later
General Procedure D: Synthesis of 1-Alkylindole-3-carboxylicAcids. A cooled (0 °C) mixture of sodium hydride (60% dispersion inmineral oil, 2.00 g, 50.0 mmol, 2.0 equiv) in DMF (30 mL) wastreated slowly with a solution of indole (2.93 g, 25 mmol) in DMF (3mL), warmed to ambient temperature, and stirred for 10 min. Themixture was cooled in an ice−water bath and then treated slowly withthe appropriate bromoalkane (26.3 mmol, 1.05 equiv). The mixturewas warmed to ambient temperature and stirred for 1 h, at which pointTLC analysis indicated complete consumption of indole. The solutionwas cooled to 0 °C and treated slowly with trifluoroacetic anhydride(8.70 mL, 62.5 mmol, 2.5 equiv). The resultant clear, red solution waswarmed to ambient temperature and stirred for 1 h, at which pointTLC analysis indicated the complete conversion of the 1-alkylindole to1-alkyl-3-trifluoroacetylindole. The reaction was poured portionwiseonto stirred ice−water (500 mL), and the mixture was vigorouslystirred at 0 °C until complete solidification of the oil layer hadoccurred. The precipitate was collected by filtration and air-dried togive crude 1-alkyl-1H-3-trifluoroacetylindoles as pink solids.A solution of crude 1-alkyl-1H-3-trifluoroacetylindole (25.0 mmol)in toluene (22 mL) was slowly added to a refluxing solution of KOH(4.63 g, 82.5 mmol, 3.3 equiv) in MeOH (8 mL), and the mixture washeated at reflux for 2 h. The mixture was cooled to ambienttemperature, and H2O (80 mL) was added. The layers were separated,and the organic layer was extracted with 1 M aq. NaOH (25 mL). Thecombined aqueous phases were acidified to pH 1 with 10 M aq. HCl,extracted with Et2O(3× 50 mL) or CH2Cl2(3 × 50 mL), and dried(MgSO4), and the solvent was evaporated. The crude products wererecrystallized from isopropanol to give analytically pure materials -
2017-04-03 at 12:19 AM UTC in Is Time An Illusion?
Originally posted by Lanny This trivializes the meaning of illusion. Bla bla bla descartes whatever, you've already accepted that perception generally, if imperfectly, tracks the noumenal world. Sure we can doubt, for brief periods and with difficulty, the truth of that proposition but in the context of someone saying "is time an illusion?" it's obvious "illusion" refers to something beyond the general capacity for fallibility of the senses, as it does in most contexts.
I'm just playing Devil's Avocado.
But if you look again, I'm not talking about Descartes and blah blah. I'm grounding that point in the concept of gauge symmetry. Our idea of what is actually "going on" is purely based on inferring "reality" by associative properties, and our "objective" version of events is one of literally infinite ways to quantify things.
I use the term noumenal only because it's convenient, my point is not philosophical but scientific. -
2017-04-02 at 11:29 PM UTC in ATTN: RisiR
- mmQ,
- aldra,
- Sophie,
- NARCassist
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2017-04-02 at 6:20 PM UTC in Can someone tell me in how many hours my ban is over?Never posted PI or spammed Bill Krozbydick you paranoid shit.
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2017-04-02 at 4:53 PM UTC in cant unsubscribe from threadsCRY HARDER FAGGOT
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2017-04-02 at 1:29 AM UTC in teh retraded thred herppppp slober fuk glum editshinHey thurrr, we gon get bannered tomorrow. This is stupid. I'll fucking kill Lanny.
This reminds me of the time I had renal failure and was at the hospital and wasn't allowed to eat and, this is not a joke, they had like some fucking waffle festival in the hospital. It smelled like a bakery in there and everyone was happy and I had a stone inside my kidney that was about to get taken out through my dick. -
2017-04-01 at 10:51 PM UTC in teh retraded thred herppppp slober fuk glum editshin
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2017-04-01 at 7:41 PM UTC in Attn: Everyone, we're getting mods!
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2017-04-01 at 7:03 AM UTC in Attn: Everyone, we're getting mods!thanks for ruining the thread captain fatherfucker
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2017-04-01 at 2:15 AM UTC in dad shoes
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2017-03-31 at 2:28 PM UTC in my life fucking sucks
Originally posted by infinityshock the fact that you considered using a vacuum in that role instead of your face hole, like any normal fag would, is strongly indicative of your own sexual experiences and preferences
Hey look. We know you think you're the "bear" in your out of the closet experience but I'm not sure this forum is right for you. You consistent sexual harassment of all of the male based users on this site gets old. Get some new material you limp wrist priss.
I have nothing against Gays but go hit on someone else. or try another troll tactic, faggot! -
2017-03-30 at 11:35 PM UTC in The taste of bloodMake her join the forum. Anyone who saw The Edgelords in their prime is a legend.
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2017-03-30 at 11:30 PM UTC in Anyone here ever had a boiled goat before, gonts?
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2017-03-30 at 11:16 PM UTC in The taste of blood"So, you like the taste of blood, huh?"
"Yea"
*Elbow to the fucking dome*
Bon appetite.... -
2017-03-30 at 11:11 PM UTC in Anyone here ever had a boil before, gonts?No but if you like it that way. My point was that Bill Krozby should be ashamed no matter what.
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2017-03-30 at 10:49 PM UTC in Somebody just told me Xanax is an amphetamine because it makes people hyperI dont use drugs I treat them nicely and date them. Its a two way relationship, we help each other out.
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2017-03-30 at 2:44 AM UTC in Green Lantern *was* like a dick without wings.
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2017-03-29 at 11:36 PM UTC in User Names
Originally posted by NARCassist how did you come up with infaggotryshack?
He pulled the dick out of his mouth and sputtered "I'm zill the zat!" and decided to become a lifelong degenerate and post on totse till the very end. In his dying days he posted Bill Krozbydick and gay rape ruining a dying board and killing what little life was left in the spirit of totse with his gay rape retardation. THats the legacy of zill the zat
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2017-03-29 at 6:57 PM UTC in Well gonts, I think this community could use a change and I have an ideaTrianglism preaches all this.. It is the true key to glory.
The people here dont want positive energy and they all hate triangles, freedom and love.
How did Zoklet get so big? I feel like I always knew about it as the kind of forum where anything goes. I would always check zoklet and shroomery for unique clandestine drug info. Our BLTC almost surpasses zoklet flasks and beakers, I take all credit.
But its 2017, nobody cares anymore. The world has gone rattex. I could have a full lab churning out total synthesis LSA clandestinely with pictures and video and it would get 0 attention. -
2017-03-29 at 4:59 PM UTC in Well gonts, I think this community could use a change and I have an ideaWe are living in a world right now where a lot of people are waking up and listening to reagan youth, whistle blowers exposing the awful. But at the same time there are just as many people maybe even more that live in a haze of fake news, reality tv shows, and I-phones.
I know a lot of us argue with each other and I'm a part of it, but I think at our collective core we can be a positive force.
We could bring more people to this community, maybe even go viral. I've made threads like this before, but we actually should do it team up and have some good clean unaltered fun.
Crack some brews on tinychat, put on nice sweaters, comb our hair and be a gang, the niggas in space doowap group or something like that.
See songs together and be jolly. Put it up on youtube on niggas in space channel and PROFIT?!
Show the world what we are all about and how we can have peace and love in world full of disease, poverty, and petty war.
Who knows we might even get laid. And I honestly think everyone here should be a part of it in some shape or form. Except for bill the cat because I honestly think he can't help himself with his one track mind.
So gonts, what do you think? We're just spit ballin here so I'm open to ideas and suggestions. But I'd eventually like to get on one direction and not have so much stuff were it spoils the broth if you know what I mean.