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The Retarded Thread: Get off that bus edition
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2021-04-13 at 3:52 AM UTC
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2021-04-13 at 11:56 AM UTC
Originally posted by Quick Mix Ready Got damn you. Its people like you that the DEA pushed Doctors to stop giving them out.
i gotchu
To a solution of 100 g (0.36 mol) 2-amino-2'-chloro-5-nitrobenzophenone in 3 L benzene is added 77.8 g (0.385 mol) bromoacetyl bromide, and with a stream of dry air bubbling through the mixture, the reaction mixture is heated at 40 C for 2 h. Thereafter, the mixture is concentrated to dryness in vacuo, leaving about 143 g (quant.) almost pure 2-(bromoacetamido)-2'-chloro-5-nitrobenzophenone.
(see swiss patent 580,087, workup: US patent 3,335,181)
The 143 g (0.36 mol) intermediate from step 2, 101 g hexamethylenetetramine (urotropine) and 36 mL 99 % formic acid are suspended/dissolved in 5 L absolute ethanol, the mixture is refluxed with stirring for 4 h, and then the mixture is concentrated in vacuo to dryness. The residue is dissolved in 2 L dichloromethane and 4 L water, the organic layer is seperated and mixed with 2 L ethanol. Over a 20 cm vigreux column, the dicloromethane is distilled off and the residual solution is cooled to 0 C for 24 h. The almost yellow-white crystalls of Clonazepam are vacuum-enhancemented off and washed with 0 C ethanol, after drying, about 90.9 g (80%) of Clonazepam are resulting, mp. 235-237°C.
how to make 2-amino-2'-chloro-5-nitrobenzophenone
A mixture of 435 g (2.485 mol) 2-chlorobenzoyl chloride and 209 g (1.53 mol) anhydrous zinc chloride is heated up to 130-140 C, and in small portions, 166 g (1.2 mol) 4-nitroaniline is added over 30 min. After complete addition, the mixture is heated up to 200-205 C (use a metal bath of Wood's alloy to heat the flask) with stirring for 1 h . After cooling to 80 C, carefully a mixture of 298 mL water and 425 mL acetic acid is added with stirring, then 553 mL 96% sulfuric acid. The mixture is heated, refluxed and stirred for 4 h and cooled to 0 C. Ammonia solution (26%) - 62 mL is added together with ice, and after recooling to room temperature, the solid is extracted into six 250 mL portions of warm (60 C) toluene. The combined toluene extract is washed exhaustively with six 250 mL portions of warm (60 C) hydrochloric acid (3 N), with six 250 mL portions of warm (60 C) 50% sodium hydroxide solution, the organic layer is dried (sodium sulfate) and evaporated to dryness in vacuo. The residue is recrystallized from petroleum ether/benzene to yield about 60g (15-20%) 2-amino-2'-chloro-5-nitrobenzophenone, mp. 118-120°C.
Toluene > p-chloro toluene > p-chloro benzaldehyde > 2-chlorobenzoyl chloride -
2021-04-13 at 1:48 PM UTC
Originally posted by Quick Mix Ready Got damn you. Its people like you that the DEA pushed Doctors to stop giving them out. You can´t get Benzos. And I get severe Panic disorders and feel like I cant breath. I have to take these from time to time. and I can´t get them filled anymore.
I never been addicted to them because I would take baby doses. Usually half of a 0.5mg or 0.25 and then take another in a few hours.
But seriously.. Damn it. Grow the hell up.
Also dont drink alcohol on them. its dangerous af
Calm down I'll send you some -
2021-04-14 at 4 PM UTCis there still a tinychat or is that over with?
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2021-04-14 at 4:15 PM UTC
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2021-04-14 at 4:17 PM UTCit was always drunks
link plz? -
2021-04-14 at 4:24 PM UTCThe following users say it would be alright if the author of this post didn't die in a fire!
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2021-04-15 at 2:19 PM UTC
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2021-04-15 at 3:10 PM UTCI'm going to book myself into a private clinic and get this fatty breast tissue cut out. I'll find some sick cunt on a cannibal forum to film themselves frying and eating it.
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2021-04-15 at 6:03 PM UTCTwo muslims were stood at the far end of the train station, probably minding their own business. Thought I'd entertain myself so told the transport officer some dodgey as fuck lookin' cunts were acting suspicious, back pack on as well, Allahu Akhbar.
Few minutes later I see them both getting dragged away kicking off. I was like, "leave them alone, they din-du-nuthin".
That's my laugh for the day, stupid bastards. -
2021-04-15 at 6:04 PM UTC
Originally posted by Robert Mugabe Two muslims were stood at the far end of the train station, probably minding their own business. Thought I'd entertain myself so told the transport officer some dodgey as fuck lookin' cunts were acting suspicious, back pack on as well, Allahu Akhbar.
Few minutes later I see them both getting dragged away kicking off. I was like, "leave them alone, they din-du-nuthin".
That's my laugh for the day, stupid bastards.
that's really fucked up if true tho.The following users say it would be alright if the author of this post didn't die in a fire! -
2021-04-15 at 6:07 PM UTC
Originally posted by Data that's really fucked up if true tho.
Well best to look at it this way, there's a 50/50 chance they could have been bombers. Don't get all mushy liberal on me now.
**IRONY** There's two Blonde, blue eyed lads with back packs taking selfies in the exact same spot unaware to the racial prejudice having taken place minutes earlier.
Britttaaaaniaaaa--- fuck-yeah!
😂😂😂 -
2021-04-15 at 6:10 PM UTC
Originally posted by Robert Mugabe Well best to look at it this way, there's a 50/50 chance they could have been bombers. Don't get all mushy liberal on me now.
**IRONY** There's two Blonde, blue eyed lads with back packs taking selfies in the exact same spot unaware to the racial prejudice having taken place minutes earlier.
Britttaaaaniaaaa— fuck-yeah!
😂😂😂
Nah dude it's not a 50/50 chance or even close
They are regular ass human beings. Like you said, probably minding their own business.
If you're gonna be a dick why don't you do it to someone you know deserves it instead of someone you think MIGHT deserve it?
50/50 is not good enough odds for me to call any sort of authority. If I tell anyone about anything, I make sure I'm 100% certain.
What were they doing to bother you? -
2021-04-15 at 6:12 PM UTC
Originally posted by Data Nah dude it's not a 50/50 chance or even close
They are regular ass human beings. Like you said, probably minding their own business.
If you're gonna be a dick why don't you do it to someone you know deserves it instead of someone you think MIGHT deserve it?
50/50 is not good enough odds for me to call any sort of authority. If I tell anyone about anything, I make sure I'm 100% certain.
What were they doing to bother you?
I don't care. If they were Neo Nazis and I could get the same result I would have done the same. -
2021-04-15 at 6:14 PM UTC
Originally posted by Data Nah dude it's not a 50/50 chance or even close
They are regular ass human beings. Like you said, probably minding their own business.
If you're gonna be a dick why don't you do it to someone you know deserves it instead of someone you think MIGHT deserve it?
50/50 is not good enough odds for me to call any sort of authority. If I tell anyone about anything, I make sure I'm 100% certain.
What were they doing to bother you?
§m£ÂgØL would never argue that normal white people didn't deserve to be fucked with.
That they were regular people.
That some rich person deserved it instead.
That they were doing nothing to bother anyone. -
2021-04-15 at 6:18 PM UTC
Originally posted by Robert Mugabe I don't care. If they were Neo Nazis and I could get the same result I would have done the same.
I would not have. I was raised to never call upon authorities for any reason. 9/10 intervention does nothing but make shit worse. If what you said is true, you caused those people trouble for absolutely no reason. IF WHAT YOU SAID IS EVEN TRUE, they coulda been good people that adhere to your values, but based on LOOKS you decided to fuck with them. How is that any better than neo-nazis? That is a shit move my dude, and if you actually did that you should feel ashamed and reflect on your actions. If you didn't do it then I guess you got me because here I am caring about some people who probably didn't even exist in the first place.
I have vodka. What do you ahve? -
2021-04-15 at 6:18 PM UTC
Originally posted by Donald Trump §m£ÂgØL would never argue that normal white people didn't deserve to be fucked with.
That they were regular people.
That some rich person deserved it instead.
That they were doing nothing to bother anyone.
Yeah I would. You're just easily trolled so you believe all the bullshit I post. -
2021-04-15 at 6:19 PM UTC
Originally posted by Data I would not have. I was raised to never call upon authorities for any reason. 9/10 intervention does nothing but make shit worse. If what you said is true, you caused those people trouble for absolutely no reason. IF WHAT YOU SAID IS EVEN TRUE, they coulda been good people that adhere to your values, but based on LOOKS you decided to fuck with them. How is that any better than neo-nazis? That is a shit move my dude, and if you actually did that you should feel ashamed and reflect on your actions. If you didn't do it then I guess you got me because here I am caring about some people who probably didn't even exist in the first place.
I have vodka. What do you ahve?
I have muslim friends. I don't fucking care. Jeez §m£ÂgØL, chill. -
2021-04-15 at 6:22 PM UTC
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2021-04-15 at 6:27 PM UTCI feel like Oct hasn't been beaten up enough in his life, or by the right people for the right reasons. I feel he's ran and told in every confrontational situation. I feel these things and yet know them to be true
