Lanny, Frala ever do this 2 u?

2024-07-13 at 2:12 AM UTC

#21

The Self Taught Man Black Hole

Originally posted by frala You’re nachos look gross and I’d hit you based on that alone.

You are nachos

You are no Jo’s

I’m gonna kill myself nkw

2024-07-13 at 2:32 AM UTC

#22

Lanny Lanny African Astronaut

Originally posted by frala You are nachos

You are no Jo’s

I’m gonna kill myself nkw

why are you quoting yourself? I'm not following this

2024-07-13 at 2:41 AM UTC

#23

The Self Taught Man Black Hole

It’s an election year and all people want to talk about is politics and global warming which makes me suicidal and as soon as the election is over nobody will care so I’m drunk bc I hate everyone and everything and nobody knows how to make nachos and also Eminem,s new album sucks so fuck your

2024-07-13 at 2:44 AM UTC

#24

Lanny Lanny African Astronaut

Originally posted by frala It’s an election year and all people want to talk about is politics and global warming which makes me suicidal and as soon as the election is over nobody will care so I’m drunk bc I hate everyone and everything and nobody knows how to make nachos and also Eminem,s new album sucks so fuck your

I know how to make awesome nachos. requires a ninja like blender to heat up cheese with season and blend it then microwave it slowly at 20% for 5 minutes for the perfect nacho sauce.

and I personally like refried for nachos but spicy black beans work great with diced onions and tomato and top with guac and sour cream. I don't like meat on mine. it's too heavy.

2024-07-13 at 2:46 AM UTC

#25

The Self Taught Man Black Hole

Of course you out chess in a blender

2024-07-13 at 2:47 AM UTC

#26

Lanny Lanny African Astronaut

Originally posted by frala Of course you out chess in a blender

nigga wut?

2024-07-13 at 2:58 AM UTC

#27

The Self Taught Man Black Hole

The following users say it would be alright if the author of this post didn't die in a fire!

CandyRein

2024-07-13 at 2:59 AM UTC

#28

Lanny Lanny African Astronaut

Originally posted by frala

Fona is saying Lanny Booted out Frala" and is posing as Frala to keep things feel normal around here. is this true? Lanny is that you? do you miss Frala lots?

2024-07-13 at 4:24 PM UTC

#29

Charles Ex Machina Space Nigga

Originally posted by Lanny Lanny Listen you racist piece of shit. Neck yourself with razor wire.

is sulphur even yellow?

i hear people say mental illness can turn sulphur green

2024-07-13 at 10:09 PM UTC

#30

Lanny Lanny African Astronaut

Originally posted by Charles Ex Machina i hear people say mental illness can turn sulphur green

is that copper you're grinding

2024-07-13 at 10:55 PM UTC

#31

CandyRein Black Hole

Originally posted by frala

😫😆

2024-07-14 at 12:16 AM UTC

#32

Bradley Florida Man

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youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck you

2024-07-14 at 12:18 AM UTC

#33

The Self Taught Man Black Hole

Oh I guess we have a wild little faggot on the loose

2024-07-14 at 12:19 AM UTC

#34

Bradley Florida Man

Yeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck youYeah nigga he said fuck 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2024-07-14 at 12:20 AM UTC

#35

The Self Taught Man Black Hole

I will fuck your front page flush in the ass

2024-07-14 at 12:20 AM UTC

#36

The Self Taught Man Black Hole

Bitch

2024-07-14 at 12:33 AM UTC

#37

the man who put it in my hood Black Hole [miraculously counterclaim my golf]

Experimental: Alternative to Al/Hg - the Al/Cu

References
There has been some talks before about using copper to activate Al:

- Woelens site talks about activating Al using CuSO4 and NaCl.
- Klute successfully reduced nitromethane to methylamine with a solution of CuSO4 and NaCl.
- On the hyperlab forums, it has been used for reductions of other compounds than nitromethane, but generally the results were unconclusive and/or low yielding.

Now, after lots of experimenting with this method (Lots of time, resources, and at least 40 test reactions ran), a general method has been found that produces approx. the same yields as one would expect from an Al/Hg. So far it's been ran successfully on a various set of nitrostyrenes. (including aromatic nitroalkenes)

Experimental
15g regular Al-foil (folded 4x, in flat strips, 2in long, 0.8in wide) was added into a 2-necked, 2L RBF. The Al-strips were made as flat as possible to avoid them floating to the surface later. 300ml EtOH, 120ml water, 45ml GAA was added in. Lastly 20g of nitrostyrene was added in. A condenser was mounted to the flask, along with a stirring rod attached on the 2nd neck, with a PTFE seal. Contents of the flask were heated to 60C. A solution of 10g CuSO4, 20g NaCl and 40ml hot water was mixed together separately. This was then added all at once to the 2L RBF, and the flask was immediately swirled around to ensure even distribution of the copper solution. Immediately, a vigorous reaction set in. During this, some Al floated to the surface. The stirring rod was lifted up by hand (without moving the PTFE seal) then pushed down on the Al in the flask, in order to keep the Al below the surface as best as possible. After 10 minutes or so, the reaction slowed down, and some Al was still left. Reflux was turned on for 1 hr, under overhead stirring. (If one does not have an overhead stirring motor, simply give the stirring rod an occasional swirl with your hands, to move the flask contents around. If one stirrs enough, then after 1 hrs, most of the Al should be gone.) The reaction was now finished and 300-400ml hot water was added whilst it was still at reflux temperature. It was then quickly re-rigged for distillation, and the alcohol was taken off. The solution was then cooled, ~130g NaOH added under mixing, and it was extracted 3x with DCM (or any solvent of choice). One can also do an in-situ steam distillation, then add acid of choice directly to the distilled water, and evaporate it in the open to be left with the salt. No need to worry about mercury fumes.

Some notes
• Generally, this reaction is a bit milder than the Al/Hg. So a larger surface area of Al can be used, and the reaction contents need to be heated a bit before the copper is added, to make it vigorous.
• It can be scaled up easily, and the amounts of CuSO4 / NaCl needed do not increase.
• It is efficient and environmentally friendly in terms of chemicals used. The alcohol is recycled, the amount of GAA used is small (45ml per 20g styrene), even the water can be recycled. If it's steam distilled, it's not neccessary to add anymore NaOH than what it takes to reach the correct PH, and no solvents would need to be used either. A lot of this possible, because one needs not worry about mercury which would otherwise contaminate everything.
• It is believed (although not 100% sure) that most copper will remain as an insoluble solid.
• It can probably be used for reductive aminations, but the CuSO4 and NaCl would possibly react with methylamine. Use of CuCl2 in place of CuSO4 and NaCl is possible.

Lastly, it should be noted that the reaction seems very tolerant and consistently produces the same yields, despite large changes in variables. For instance, in the beginning, this reaction was ran with 20g styrene in 250ml water, 250ml GAA, 250ml EtOH in an open beaker, with 50g CuSO4 and 100g NaCl dissolved in. This reaction was a mess, and there was a large amount of green precipitate at the bottom even before it began. Then 5g Al foil at a time, packed together by hand, was held into the reaction with a metal tool. The aluminum was eaten up with vengance, and the solution was boiling hard and solvent actively escaped into the open, and had to be replaced constantly. Nontheless, a total of 40g Al was consumed. And even here, yields were the same (~70%) as with the above reaction.