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teh retraded thred herppppp slober fuk glum editshin
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2017-04-03 at 12:17 AM UTC
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2017-04-03 at 12:23 AM UTC
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2017-04-03 at 12:31 AM UTChooooooooooows wsepp
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2017-04-03 at 1:22 AM UTCYou told me beefore, we're over
You
Gave
Me
The Cold shoulder
Now my pockets
Like boulders
But fuck you you fucked me over
PS Its hilarious that people have been coming to this site or its predecessors for years and years just to bicker with strangers. -
2017-04-03 at 1:27 AM UTC
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2017-04-03 at 1:29 AM UTC
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2017-04-03 at 1:30 AM UTC
Originally posted by WS i be smokin synthetic broccoli on bundy they say its goood for my heallth.
i remember you saying "i laid down next to a subwoofer and turned into a triangle like"
this blew my mind and the next day i smoked a bag of spice on 840mg of coricidin and had a seizure in my own vomit right after i turned into a triangle
this is one of the many events that created the perfect storm for trianglism's dogma, so thanks WS -
2017-04-03 at 1:32 AM UTC
Originally posted by WS You told me beefore, we're over
You
Gave
Me
The Cold shoulder
Now my pockets
Like boulders
But fuck you you fucked me over
PS Its hilarious that people have been coming to this site or its predecessors for years and years just to bicker with strangers.
Is it? Is it HILARIOUS? Does it make you laugh WITHOUT CONTROL? Are you DOUBLED OVER IN PAIN FROM THE HILARIOUSNESS OF IT ALL? Huh? HUH???!! -
2017-04-03 at 1:36 AM UTCvomit triangles are the most legit ones
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2017-04-03 at 1:42 AM UTCWould 'knuckle-ass shitlord' be a good insult irl?
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2017-04-03 at 1:43 AM UTCno
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2017-04-03 at 1:44 AM UTCThat's what I figured. What about 'pillowfaced fuckbottle'?
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2017-04-03 at 1:47 AM UTCIf you called me any of these I would think you are a homosexual.
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2017-04-03 at 1:51 AM UTCSo what you're saying is 'sour-lipped bitch-bottom' wouldn't set you into a rage? I should just stick to the standard pussy ass faggots and punk bitch cuck motherfuckers?
Mark ass tricks and tricks ass marks. -
2017-04-03 at 1:57 AM UTCtime to switch gimmicks
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2017-04-03 at 1:58 AM UTC
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2017-04-03 at 2:01 AM UTC
Originally posted by mmQ So what you're saying is 'sour-lipped bitch-bottom'
id smack you for dat one
I gotta leave this here for storage I will pick it up later
General Procedure D: Synthesis of 1-Alkylindole-3-carboxylicAcids. A cooled (0 °C) mixture of sodium hydride (60% dispersion inmineral oil, 2.00 g, 50.0 mmol, 2.0 equiv) in DMF (30 mL) wastreated slowly with a solution of indole (2.93 g, 25 mmol) in DMF (3mL), warmed to ambient temperature, and stirred for 10 min. Themixture was cooled in an ice−water bath and then treated slowly withthe appropriate bromoalkane (26.3 mmol, 1.05 equiv). The mixturewas warmed to ambient temperature and stirred for 1 h, at which pointTLC analysis indicated complete consumption of indole. The solutionwas cooled to 0 °C and treated slowly with trifluoroacetic anhydride(8.70 mL, 62.5 mmol, 2.5 equiv). The resultant clear, red solution waswarmed to ambient temperature and stirred for 1 h, at which pointTLC analysis indicated the complete conversion of the 1-alkylindole to1-alkyl-3-trifluoroacetylindole. The reaction was poured portionwiseonto stirred ice−water (500 mL), and the mixture was vigorouslystirred at 0 °C until complete solidification of the oil layer hadoccurred. The precipitate was collected by filtration and air-dried togive crude 1-alkyl-1H-3-trifluoroacetylindoles as pink solids.A solution of crude 1-alkyl-1H-3-trifluoroacetylindole (25.0 mmol)in toluene (22 mL) was slowly added to a refluxing solution of KOH(4.63 g, 82.5 mmol, 3.3 equiv) in MeOH (8 mL), and the mixture washeated at reflux for 2 h. The mixture was cooled to ambienttemperature, and H2O (80 mL) was added. The layers were separated,and the organic layer was extracted with 1 M aq. NaOH (25 mL). Thecombined aqueous phases were acidified to pH 1 with 10 M aq. HCl,extracted with Et2O(3× 50 mL) or CH2Cl2(3 × 50 mL), and dried(MgSO4), and the solvent was evaporated. The crude products wererecrystallized from isopropanol to give analytically pure materials -
2017-04-03 at 2:02 AM UTCThank you.
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2017-04-03 at 2:04 AM UTCFor the synthesis of syncans or threatning to hit yo?.
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2017-04-03 at 2:08 AM UTC